Abatement efficiency and fate of EPA-Listed PAHs in aqueous medium under simulated solar and UV-C irradiations, and combined process with TiO2 and H2O2

Navid Kargar; Ali Reza Amani-ghadim; Amir Abbas Matin; Golnar Matin; Hasan Baha Buyukisik

doi:10.12714/egejfas.37.1.03

EN

Abatement efficiency and fate of EPA-Listed PAHs in aqueous medium under simulated solar and UV-C irradiations, and combined process with TiO2 and H2O2

Abstract

Photolytic degradation of dissolved compounds of 16 EPA-Listed PAHs in aqueous medium, exposed to ultraviolet/ titanium dioxide (UV-C/TiO₂), xenon light/ titanium dioxide (Xe/TiO₂), xenon light/ hydrogen peroxide (Xe/H₂O₂) and ultraviolet/ hydrogen peroxide (UV-C/H₂O₂) was studied. The compounds which detected above detection limit of applied analytical method and instrument include: naphthalene (Nap), acenaphthylene (Acy), acenaphthene (Ace), fluorene (Flu), fluoranthene (Fln) and pyrene (Pyr) survived. A time-course experiment (0, 1, 2, 5, 12 min) was performed to determine the fate of PAHs profile along treatments. After accomplishment of the removal process ∑₆ PAHs ranked as follow: UV-C/TiO₂ > Xe/TiO₂ > UV-C > Xe > Xe/H₂O₂, and UV-C /H₂O₂ with estimated values of 76.38, 23.02, 22.55, 2.78, 0.00 and 0.00% of the concentration values at the beginning of the treatment, respectively. High efficiency of Xe/H₂O₂ treatment process (100.00%) at the end of treatment and the structure of residual PAHs which changed to the lighter compounds (2,3-ringed PAHs) before accomplishment of the removal process were proven. Generally, low resistance of Fln to all treatment conditions was observed. Total removal of Nap was considered to be a characteristic PAH compound for completion of the removal of PAHs. Mutate of parent PAH compounds and intermediates were analyzed by gas chromatography-mass spectrometry (GC-MS) and the results suggest the evaluating the toxicity of the treated water due to by-product formation concerns.

Keywords

Water treatment,advanced oxidation processes (AOPs),photodegradation,endocrine disrupting chemicals (EDCs),16 EPA-Listed PAHs

Destekleyen Kurum

Ege University

Proje Numarası

2017/SÜF/014

Teşekkür

This study was partially funded by Ege University Scientific Research (BAP) (Project No.: 2017/SÜF/014). Authors acknowledge Dr. Ozan Ünsalan (Ege University, Department of Physics) for his help with the analysis of Raman spectra. Navid Kargar and Golnar Matin thank Prof. Yury Gogotsi (A.J. Drexel Nanotechnology Institute, Drexel University) for his useful comments and suggestions on characterization of TiO2 nanocrystals.

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Çevre Bilimleri

Bölüm

Araştırma Makalesi

Yazarlar

Navid Kargar ^*
0000-0002-6939-0284
Türkiye

Ali Reza Amani-ghadim
0000-0003-3279-5170
Iran

Amir Abbas Matin
0000-0001-8264-8414
Iran

Golnar Matin
0000-0002-1286-8611
Türkiye

Hasan Baha Buyukisik
0000-0002-5855-4300
Türkiye

Yayımlanma Tarihi

15 Mart 2020

Gönderilme Tarihi

9 Nisan 2019

Kabul Tarihi

5 Eylül 2019

Yayımlandığı Sayı

Yıl 1970 Cilt: 37 Sayı: 1

DOI

https://doi.org/10.12714/egejfas.37.1.03

IZ

https://izlik.org/JA65SX34UH

Kaynak Göster

RIS / Bibtex

APA

Kargar, N., Amani-ghadim, A. R., Matin, A. A., Matin, G., & Buyukisik, H. B. (2020). Abatement efficiency and fate of EPA-Listed PAHs in aqueous medium under simulated solar and UV-C irradiations, and combined process with TiO2 and H2O2. Ege Journal of Fisheries and Aquatic Sciences, 37(1), 15-27. https://doi.org/10.12714/egejfas.37.1.03

Cited By

Evaluation of OH Radical Reaction Positions in 3-Ring PAHs Using Transition State Energy and Atomic Charge Calculations

Applied Sciences

https://doi.org/10.3390/app12052479

Machine learning-driven surface water quality prediction: an intuitive GUI solution for forecasting TDS and DO levels

Water Quality Research Journal

https://doi.org/10.2166/wqrj.2025.005

Öz

Abatement efficiency and fate of EPA-Listed PAHs in aqueous medium under simulated solar and UV-C irradiations, and combined process with TiO2 and H2O2

Abstract

Keywords

Destekleyen Kurum

Proje Numarası

Teşekkür

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster

Cited By

Evaluation of OH Radical Reaction Positions in 3-Ring PAHs Using Transition State Energy and Atomic Charge Calculations

Machine learning-driven surface water quality prediction: an intuitive GUI solution for forecasting TDS and DO levels