Araştırma Makalesi
Determination of Metal Concentrations in Değirmendere Stream Drainage Area of Southeastern Black Sea Coast of Turkey
Öz
Bu çalışmanın amacı Güneydoğu Karadeniz’in Türkiye kıyılarında denize boşalan Değirmendere deresinin drenaj alanında sedimentteki metal derişimlerinin ve zenginleşme düzeylerinin belirlenmesidir. Çalışmada 5 ayrı istasyondan üç arklı mevsimde yüzey sediment örnekleri Ekman Grap kullanılarak alınmıştır. Sedimentteki V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, Al ve Fe derişimleri mikrodalga sistemde çözünürleştirildikten sonra ICP-MS ile ölçülmüştür.
Metal derişimleri açısından istasyonlar arasındaki farklılık istatistiksel olarak anlamlı düzeyde değildir (p>0.05). Ancak nehir ağzına yakın konumda bulunan 1 nolu istasyonda bazı metallerin (Fe, Mn, Co, Ni, Cu, Zn, V) derişimleri diğer istasyonlardan nispeten daha yüksek bulunmuştur.
Aluminyum normlizasyonu sonucunda tespit edilen zenginleşme düzeyleri V için 1,5-2,1; Cr için 0,6-1,0; Mn için 0,8-1,7; Fe için 1,1-1,7; Co için 1,1-2,0; Ni için 0,4-0,9; Cu için 1,3-2,3; Zn için 1,4-3,9; As için 0,8-1,4; Cd için 0,5-4,1 ve Pb için 0,9-4,2 aralığında bulunmuştur. Bazı istasyonlarda Cu, Zn ve Pb elementlerinin orta derecede zenginleşme gösterdiği tespit edilmiştir.
Anahtar Kelimeler
Destekleyen Kurum
Karadeniz Teknik Üniversitesi
Proje Numarası
FAY-2017-5767
Teşekkür
This study is supported by a grant from Karadeniz Technical University. Scientific Research Project (Project Number: FAY-2017-5767)
Kaynakça
- Sastre, J., Vidal, A., Rauret, G., 2002. Determination of Cd, Cu, Pb and Zn in Environmental Samples: Microwave – Assisted Total Digestion Versus Aqua Regia and Nitric Acid Extraction, Analytica Chimica Acta.,462, 59 – 72.
- Krishna, A. K., Satyanarayanan, M., Govil, P. K., 2009. Assessment of Heavy Metal Pollution in Water Using Multivariate Statistical Techniques in an Industrial Area: a Case Study from Patancheru, Medak District, Andhra Pradesh, India, J. Hazard. Mater. 167, 366-373.
- Varol, M.., 2011. Assessment of Heavy Metal Contamination in Sediments of the Tigris River (Turkey) Using Pollution Indices and Multivariate Statistical Techniques, J. Hazard. Mater. 195, 355--364.
- Iwasaki, Y., Kagaya, T., Miyamoto, K.I., Matsuda, H., 2009. Effects of heavy metals on riverine benthic macroinvertebrate assemblages with reference to potential food availability for drift-feeding fishes. Environ. Toxicol. Chem. 28 (2), 354–363.
- Bentum, J.K., Anang, M., Boadu, K.O., Koranteng-Addo, E.J., Antwi, E.O., 2011. Assessment of heavy metals pollution of sediments from Fosu Lagoon in Ghana. Bull. Chem. Soc. Ethiop. 25 (2), 191–196.
- Shikazono, N., Tatewaki, M.K, Nakano, T., Zakir, H.M., 2012. Sources, spatial variation, and speciation of heavy metals in sediment of the Tamagawa River in Central Japan, Environ. Geochem. Health., 34, 13-26.
- Schintu, M., Degetto, S., 1999. Sedimentary records of metals in the industrial harbour of pordevesme, Sardinia (Italy), The Science of the Total Environment, 241: 129-141.
- Gültekin, F., Dilek, R., Ersoy, A. F., Ersoy, H. (2005). Aşağı Değirmendere (Trabzon) Havzasındaki Suların Kalitesi. Jeoloji Mühendisliği Dergisi 29 (1), 21-34.
- Kwon, Y.T., Lee, C.W., 2001. Sedimentation pattern and sediments bioavailability in a wastewater discharging area by sequential metal analysis. Microchem. J., 68 (2-3), 135-141.
- Csuros, M., Csuros, C., 2002. Environmental sampling and analysis for metals. Lewis, Boca Raton.
- Cukrov, N., Franciskovic-Bilinski, S., Hlaca, B. & Barisic, D. 2011. A recent history of metal accumulation in the sediments of Rijeka harbor, Adriatic Sea, Croatia, Marine pollution bulletin. 62, 1, 154-167Turekian KK, Wedephol KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72:175–192
- Turekian, K.K. and Wedepohl, K.H. (1961). Distribution of the Elements in some major units of the Earth's crust. Geological Society of America, Bulletin 72: 175-192.
- Alkan, N., Alkan, A., Akbaş, U., Fisher, A. (2015) Metal Pollution Assessment in Sediments of the Southeastern Black Sea Coast of Turkey. Soil and Sediment Contamination: An International Journal. 24:3, 290-305. DOI: 10.1080/15320383.2015.950723
- Alkan. A., Serdar. S., Fidan. D., Akbaş. U., Zengin. B., & Kılıç. M.B. (2013). Physico-Chemical Characteristics and Nutrient Levels of the Eastern Black Sea Rivers. Turkish Journal of Fisheries and Aquatic Sciences. 13, 847-859. http://doi.org/10.4194/1303-2712-v13_5_09
- Özşeker, K., Erüz, C., Cılız, S., Mani, F. (2014). Assessment of Heavy Metal Contribution and Associated Ecological Risk in the Coastal Zone Sediments of the Black Sea:Trabzon. Clean-Soil,Air, Water. 42(10), 1477-1482.
- Özşeker, K., Seyhan, K., Erüz, C. (2016). Ecological Risk Assessment and Spatial Distribution of Heavy Metals in Sediment and Pore Water around Trabzon Harbor, Turkey. Fresenius Environment Bulletin. 8, 3125-3133.
Yıl 2021,
Sayı: 2 - Special Issue for 2nd International Environmental Chemistry Congress, 117 - 124, 08.02.2021
Öz
Proje Numarası
FAY-2017-5767
Kaynakça
- Sastre, J., Vidal, A., Rauret, G., 2002. Determination of Cd, Cu, Pb and Zn in Environmental Samples: Microwave – Assisted Total Digestion Versus Aqua Regia and Nitric Acid Extraction, Analytica Chimica Acta.,462, 59 – 72.
- Krishna, A. K., Satyanarayanan, M., Govil, P. K., 2009. Assessment of Heavy Metal Pollution in Water Using Multivariate Statistical Techniques in an Industrial Area: a Case Study from Patancheru, Medak District, Andhra Pradesh, India, J. Hazard. Mater. 167, 366-373.
- Varol, M.., 2011. Assessment of Heavy Metal Contamination in Sediments of the Tigris River (Turkey) Using Pollution Indices and Multivariate Statistical Techniques, J. Hazard. Mater. 195, 355--364.
- Iwasaki, Y., Kagaya, T., Miyamoto, K.I., Matsuda, H., 2009. Effects of heavy metals on riverine benthic macroinvertebrate assemblages with reference to potential food availability for drift-feeding fishes. Environ. Toxicol. Chem. 28 (2), 354–363.
- Bentum, J.K., Anang, M., Boadu, K.O., Koranteng-Addo, E.J., Antwi, E.O., 2011. Assessment of heavy metals pollution of sediments from Fosu Lagoon in Ghana. Bull. Chem. Soc. Ethiop. 25 (2), 191–196.
- Shikazono, N., Tatewaki, M.K, Nakano, T., Zakir, H.M., 2012. Sources, spatial variation, and speciation of heavy metals in sediment of the Tamagawa River in Central Japan, Environ. Geochem. Health., 34, 13-26.
- Schintu, M., Degetto, S., 1999. Sedimentary records of metals in the industrial harbour of pordevesme, Sardinia (Italy), The Science of the Total Environment, 241: 129-141.
- Gültekin, F., Dilek, R., Ersoy, A. F., Ersoy, H. (2005). Aşağı Değirmendere (Trabzon) Havzasındaki Suların Kalitesi. Jeoloji Mühendisliği Dergisi 29 (1), 21-34.
- Kwon, Y.T., Lee, C.W., 2001. Sedimentation pattern and sediments bioavailability in a wastewater discharging area by sequential metal analysis. Microchem. J., 68 (2-3), 135-141.
- Csuros, M., Csuros, C., 2002. Environmental sampling and analysis for metals. Lewis, Boca Raton.
- Cukrov, N., Franciskovic-Bilinski, S., Hlaca, B. & Barisic, D. 2011. A recent history of metal accumulation in the sediments of Rijeka harbor, Adriatic Sea, Croatia, Marine pollution bulletin. 62, 1, 154-167Turekian KK, Wedephol KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72:175–192
- Turekian, K.K. and Wedepohl, K.H. (1961). Distribution of the Elements in some major units of the Earth's crust. Geological Society of America, Bulletin 72: 175-192.
- Alkan, N., Alkan, A., Akbaş, U., Fisher, A. (2015) Metal Pollution Assessment in Sediments of the Southeastern Black Sea Coast of Turkey. Soil and Sediment Contamination: An International Journal. 24:3, 290-305. DOI: 10.1080/15320383.2015.950723
- Alkan. A., Serdar. S., Fidan. D., Akbaş. U., Zengin. B., & Kılıç. M.B. (2013). Physico-Chemical Characteristics and Nutrient Levels of the Eastern Black Sea Rivers. Turkish Journal of Fisheries and Aquatic Sciences. 13, 847-859. http://doi.org/10.4194/1303-2712-v13_5_09
- Özşeker, K., Erüz, C., Cılız, S., Mani, F. (2014). Assessment of Heavy Metal Contribution and Associated Ecological Risk in the Coastal Zone Sediments of the Black Sea:Trabzon. Clean-Soil,Air, Water. 42(10), 1477-1482.
- Özşeker, K., Seyhan, K., Erüz, C. (2016). Ecological Risk Assessment and Spatial Distribution of Heavy Metals in Sediment and Pore Water around Trabzon Harbor, Turkey. Fresenius Environment Bulletin. 8, 3125-3133.
Toplam 16 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Articles |
| Yazarlar | |
| Proje Numarası | FAY-2017-5767 |
| Yayımlanma Tarihi | 8 Şubat 2021 |
| Kabul Tarihi | 9 Aralık 2020 |
| Yayımlandığı Sayı | Yıl 2021 Sayı: 2 - Special Issue for 2nd International Environmental Chemistry Congress |
Kaynak Göster
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