Determination of Organic Chlorinated Pesticide, Polychlorinated Diphenylether and Polychlorinated Biphenyl Compounds in Water Samples from Egirdir Lake
Öz
The most persistent organic compounds are organic chlorinated pesticides, polychlorinated diphenyl ethers and polychlorinated biphenyls, which have adverse effects on human, animal and environmental health. Egirdir lake is fourth-largest lake of Turkey that is located in Mediterranean area between Sultan and Karakus mountains in the province of Isparta. Crayfish hunting and trout farming are performed in this lake and these products are offered to the domestic and foreign market. Therefore, it is important for public health and economic reasons that this lake is not contaminated by pollutants. In this study, 192 water samples which were collected from 48 points during one year between January 2018 and December 2018 were investigated regarding the presence of a total of 23 organic compounds including 9 organic chlorinated pesticides (hexachlorocyclohexane, beta-hexachlorocyclohexane, gamma-hexachlorocyclohexane, hexachlorobenzene, 4,4’-dichlorodiphenyldichloroethane, 4,4’-dichloro diphenyldichloroethylene, 2,4’-dichlorodiphenyltrichloroethane, 4,4’-dichlorodiphenyltrichloroethane, heptachlor and methoxychlor), 8 polychlorinated diphenylethers (28, 30, 52, 101, 118, 138, 153, 180 ve 209) and 6 polychlorinated biphenyls (17, 47, 66, 100, 153, 183) by means of GC-MS. In the study, it was determined that none of the water samples taken from Egirdir Lake contained persistent organic compounds. This shows that Lake Egirdir is clean for organic pollutants and does not pose a threat to the lake ecosystem.
Anahtar Kelimeler
Organic Chlorinated Pesticides Polychlorinated Diphenylethers Polychlorinated Biphenyls Egirdir Lake
Kaynakça
- Acaroz U., Arslan-Acaroz D., Ince S. 2019. A Wide Perspective on Nutrients in Beverages. In Nutrients in Beverages. Academic Press, p. 1-39.
- Gray J.S. 2002. Biomagnification in marine systems: the perspective of an ecologist. Marine Pollution Bulletin, 45 (1-12): 46-52.
- Google maps. Eğirdir Gölü. Erişim: https://www.google.com/maps/place/E%C4%9Firdir+G%C3%B6l%C3%BC/@38.0611707,30.5760993,10z Erişim Tarihi:16.01.2020
- Han D. ve Currell M.J. 2017. Persistent organic pollutants in China's surface water systems. Science of the Total Environment, 580: 602-625.
- Jones K.C., De Voogt P. 1999. Persistent organic pollutants (POPs): state of the science. Environmental pollution, 100 (1-3): 209-221.
- Kuzukiran O., Yurdakok-Dikmen B., Totan F.E., Celik C., Orhan E.C., Bilir E K, Kara E. Filazi, A. 2016. Analytical method development and validation for some persistent organic pollutants in water and sediments by gas chromatography mass spectrometry. International Journal of Environmental Research, 10 (3): 401-410.
- Kuzukiran O., Yurdakok-Dikmen B., Sevin S., Sireli U.T., Iplikcioglu-Cil G., Filazi A. 2018. Determination of selected endocrine disruptors in organic, free-range, and battery- produced hen eggs and risk assessment. Environmental Science and Pollution Research, 25(35): 35376-35386.
- Kuzukiran Ö., Filazi A., Arslan P., Yurdakök-Dikmen B., Tavşanoğlu Ü.N.Y. 2019. Kızılırmak Nehri’nden Alınan Su ve Sediment Örneklerinde Kalıcı Organik Kirleticilerin Tespiti. Kocatepe Veteriner Dergisi, 12 (4): 430-438.
- Magnusson B., Ornemark U. 2014. The fitness for purpose of analytical methods: a laboratory guide to method validation and related topics. 57.
- Malik A., Ojha P., Singh K. P. 2009. Levels and distribution of persistent organochlorine pesticide residues in water and sediments of Gomti River (India)-a tributary of the Ganges River. Environmental Monitoring and Assessment, 148 (1-4): 421-435.
- Milun V., Lušić J., Despalatović M. 2016. Polychlorinated biphenyls, organochlorine pesticides and trace metals in cultured and harvested bivalves from the eastern Adriatic coast (Croatia). Chemosphere, 153: 18-27.
- Naushad M. 2014. Surfactant assisted nano-composite cation exchanger: Development, characterization and applications for the removal of toxic Pb2+ from aqueous medium. Chemical Engineering Journal, 235: 100-108.
- Paumo H.K., Das R., Bhaumik M., Maity, A. 2020. Visible-Light-Responsive Nanostructured Materials for Photocatalytic Degradation of Persistent Organic Pollutants in Water. In Green Methods for Wastewater Treatment. Springer, Cham. p. 1-29.
- Ünal, E.D. 2010. Kuzey Doğu Akdeniz'de (Mersin Körfezi) deniz suyu, sediman ve biyotada organik klorlu pestisit kirlilik düzeyinin araştırılması. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Çevre Mühendisliği Anabilim Dalı, Doktora Tezi.
- Verhaert V. Newmark N., D’Hollander W., Covaci A, Vlok W., Wepener V., Addo-Bediako A., Jooste A., Teuchies J., Blust R., Bervoets L. 2017 Persistent organic pollutants in the Olifants River Basin, South Africa: bioaccumulation and trophic transfer through a subtropical aquatic food web. Sci Total Environ 586:792–806.
Eğirdir Gölü ve Çevresindeki Kaynak Sularından Alınan Su Örneklerinde Organik Klorlu Pestisit, Polibromlu Difenil Eter ve Poliklorlu Bifenil Bileşiklerinin Belirlenmesi
Öz
Kalıcılığı en çok gözlenen organik bileşikler, organik klorlu pestisitler, poliklorlu difenileter ve poliklorlu bifeniller olup bunların insan, hayvan ve çevre sağlığına olumsuz etkileri söz konusu olmaktadır. Eğirdir gölü Akdeniz bölgesinde Isparta ili sınırları içerisinde Sultan ve Karakuş Dağları'nın arasında yer alan Türkiye’nin dördüncü büyük gölüdür. Bu gölde kerevit avlanması ve alabalık yetiştiriciliği yapılmakta olup ve bu ürünler iç ve dış piyasaya sunulmaktadır. Bu nedenle, bu gölün kirleticiler açısından kontamine olmaması halk sağlığı ve ekonomik açıdan önem arz etmektedir. Bu çalışmada Ocak 2018 ile Aralık 2018 tarihleri arasındaki 1 yıl boyunca ve mevsimsel olarak 48 noktadan toplanan 192 su örneğinde 9 organik klorlu pestisit (alfa-hekzaklorosiklohekzan, beta-hekzaklorosiklohekzan, gama-hekzaklorosiklohekzan, hekzaklorobenzen, 4,4’-diklorodifenil dikloroetan, 4,4’-diklorodifenil dikloroetilen, 2,4’-diklorodifenil trikloroetan, 4,4’-diklorodifenil trikloroetan, heptaklor ve metoksiklor), 8 poliklorlu difenileter (28, 30, 52, 101, 118, 138, 153, 180 ve 209) ve 6 poliklorlu bifeniller (17, 47, 66, 100, 153, 183) olmak üzere toplam 23 organik bileşiklerin miktarları araştırılarak bunların mevsimsel olarak varlığının GC-MS cihazında araştırıldı. Yapılan çalışmada eğirdir gölünden alınan su örneklerinin hiç birinde kalıcı organik varlığına rastlanılmamıştır. Bu durum, eğirdir gölünün organik kirleticiler yönünden temiz olduğunu ve göl ekosistemi üzerinde tehlike arz etmediğini göstermektedir.
Anahtar Kelimeler
Organik klorlu pestisitler poliklorlu difenileterler poliklorlu bifeniller Eğirdir Gölü.
Kaynakça
- Acaroz U., Arslan-Acaroz D., Ince S. 2019. A Wide Perspective on Nutrients in Beverages. In Nutrients in Beverages. Academic Press, p. 1-39.
- Gray J.S. 2002. Biomagnification in marine systems: the perspective of an ecologist. Marine Pollution Bulletin, 45 (1-12): 46-52.
- Google maps. Eğirdir Gölü. Erişim: https://www.google.com/maps/place/E%C4%9Firdir+G%C3%B6l%C3%BC/@38.0611707,30.5760993,10z Erişim Tarihi:16.01.2020
- Han D. ve Currell M.J. 2017. Persistent organic pollutants in China's surface water systems. Science of the Total Environment, 580: 602-625.
- Jones K.C., De Voogt P. 1999. Persistent organic pollutants (POPs): state of the science. Environmental pollution, 100 (1-3): 209-221.
- Kuzukiran O., Yurdakok-Dikmen B., Totan F.E., Celik C., Orhan E.C., Bilir E K, Kara E. Filazi, A. 2016. Analytical method development and validation for some persistent organic pollutants in water and sediments by gas chromatography mass spectrometry. International Journal of Environmental Research, 10 (3): 401-410.
- Kuzukiran O., Yurdakok-Dikmen B., Sevin S., Sireli U.T., Iplikcioglu-Cil G., Filazi A. 2018. Determination of selected endocrine disruptors in organic, free-range, and battery- produced hen eggs and risk assessment. Environmental Science and Pollution Research, 25(35): 35376-35386.
- Kuzukiran Ö., Filazi A., Arslan P., Yurdakök-Dikmen B., Tavşanoğlu Ü.N.Y. 2019. Kızılırmak Nehri’nden Alınan Su ve Sediment Örneklerinde Kalıcı Organik Kirleticilerin Tespiti. Kocatepe Veteriner Dergisi, 12 (4): 430-438.
- Magnusson B., Ornemark U. 2014. The fitness for purpose of analytical methods: a laboratory guide to method validation and related topics. 57.
- Malik A., Ojha P., Singh K. P. 2009. Levels and distribution of persistent organochlorine pesticide residues in water and sediments of Gomti River (India)-a tributary of the Ganges River. Environmental Monitoring and Assessment, 148 (1-4): 421-435.
- Milun V., Lušić J., Despalatović M. 2016. Polychlorinated biphenyls, organochlorine pesticides and trace metals in cultured and harvested bivalves from the eastern Adriatic coast (Croatia). Chemosphere, 153: 18-27.
- Naushad M. 2014. Surfactant assisted nano-composite cation exchanger: Development, characterization and applications for the removal of toxic Pb2+ from aqueous medium. Chemical Engineering Journal, 235: 100-108.
- Paumo H.K., Das R., Bhaumik M., Maity, A. 2020. Visible-Light-Responsive Nanostructured Materials for Photocatalytic Degradation of Persistent Organic Pollutants in Water. In Green Methods for Wastewater Treatment. Springer, Cham. p. 1-29.
- Ünal, E.D. 2010. Kuzey Doğu Akdeniz'de (Mersin Körfezi) deniz suyu, sediman ve biyotada organik klorlu pestisit kirlilik düzeyinin araştırılması. Mersin Üniversitesi, Fen Bilimleri Enstitüsü, Çevre Mühendisliği Anabilim Dalı, Doktora Tezi.
- Verhaert V. Newmark N., D’Hollander W., Covaci A, Vlok W., Wepener V., Addo-Bediako A., Jooste A., Teuchies J., Blust R., Bervoets L. 2017 Persistent organic pollutants in the Olifants River Basin, South Africa: bioaccumulation and trophic transfer through a subtropical aquatic food web. Sci Total Environ 586:792–806.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Mühendislik |
| Bölüm | Araştırma Makalesi |
| Yazarlar | |
| Yayımlanma Tarihi | 15 Haziran 2020 |
| Gönderilme Tarihi | 16 Ocak 2020 |
| Kabul Tarihi | 4 Şubat 2020 |
| Yayımlandığı Sayı | Yıl 2020 Cilt: 9 Sayı: 2 |
