Research Article
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Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid

Year 2022, Volume: 10 Issue: 1, 154 - 169, 31.01.2022
https://doi.org/10.29130/dubited.970641

Abstract

In this study, it was aimed to synthesize and characterize a new polymeric cryogel system to be formed with polymeric linoleic acid (PLina), a vegetable oil-based polymeric fatty acid, and the widely preferred 2-hydroxyethyl methacrylate (HEMA) monomer. cryogels. For this purpose, firstly, autoxidation and hydroxylation reactions were carried out for polymeric lineloic acid, respectively. Hydroxylated polymeric lineloic acid (PLina-OH) and HEMA monomer were subjected to a cryogenic gelation reaction in the presence of N,N′-methylene bisacrylamide (MBAA) as crosslinking agent. The obtained new cryogel was characterized by FTIR, SEM, BET, TGA analyses. The swelling behavior of the synthesized PLinaOH-HEMA cryogels in water was concluded with kinetic studies. In the other hands, some of polar and non-polar other solvents was used for investigation of all cryogels to see their potentials for solvent uptake.

Supporting Institution

Düzce University Scientific Research Projects

Project Number

2019.05.03.1024

Thanks

This study was supported by Düzce University Scientific Research Projects (Grant/Award Number: 2019.05.03.1024).

References

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Polimerik Linoleik Asit Içeren HEMA Bazlı Amfifilik Yarı IPN Kriyojellerin Hazırlanması, Karakterizasyonu ve Şişme Davranışının Araştırılması

Year 2022, Volume: 10 Issue: 1, 154 - 169, 31.01.2022
https://doi.org/10.29130/dubited.970641

Abstract

Bu çalışmada, bitkisel yağ bazlı bir polimerik yağ asidi olan polimerik linoleik asit (PLina) ve yaygın olarak tercih edilen 2-hidroksietil metakrilat (HEMA) monomeri ile oluşturulacak yeni bir polimerik kriyojel sisteminin sentezlenmesi ve karakterize edilmesi amaçlanmıştır. Bu amaçla, öncelikle polimerik lineloik asit için sırasıyla otooksidasyon ve hidroksilasyon reaksiyonları gerçekleştirilmiştir. Hidroksillenmiş polimerik lineloik asit ve HEMA monomer, çapraz bağlayıcı olarak MBAA varlığında bir kriyojenik jelleşme reaksiyonuna tabi tutuldu. Elde edilen yeni kriyojeller, FTIR, SEM, BET, TGA analizleri ile karakterize edilmiştir. Sentezlenen PLinaOH-HEMA kriyojellerinin sudaki şişme davranışı kinetik çalışmalarla sonuçlandırılmıştır. Öte yandan, tüm kriyojellerin çözücü alımı için potansiyellerini görmek için araştırmak için bazı polar ve polar olmayan diğer çözücüler kullanıldı.

Project Number

2019.05.03.1024

References

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  • [2] J. Jagur-Grodzinski, “Polymeric gels and hydrogels for biomedical and pharmaceutical applications,” Polymers for Advanced Technologies, vol. 21, no. 1. pp. 27–47, 2010.
  • [3] N. Sahiner, “Soft and flexible hydrogel templates of different sizes and various functionalities for metal nanoparticle preparation and their use in catalysis,” Progress in Polymer Science, vol. 38, no. 9. Pergamon, pp. 1329–1356, Sep. 01, 2013.
  • [4] F. Horkay and J. F. Douglas, “Polymer Gels: Basics, Challenges, and Perspectives,” 2018. Accessed: Jun. 22, 2021. [Online]. Available: https://pubs.acs.org/sharingguidelines.
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  • [9] F. M. Plleva, I. Y. Galaev, and B. Mattiasson, “Macroporous gels prepared at subzero temperatures as novel materials for chromatography of particulate-containing fluids and cell culture applications,” Journal of Separation Science, vol. 30, no. 11. pp. 1657–1671, 2007.
  • [10] M. Zhai, F. Ma, J. Li, B. Wan, and N. Yu, “Preparation and properties of cryogel based on poly(hydroxypropyl methacrylate),” J. Biomater. Sci. Polym. Ed., vol. 29, no. 12, pp. 1401–1425, 2018.
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  • [16] T. Kangkamano, A. Numnuam, W. Limbut, P. Kanatharana, and P. Thavarungkul, “Chitosan cryogel with embedded gold nanoparticles decorated multiwalled carbon nanotubes modified electrode for highly sensitive flow based non-enzymatic glucose sensor,” Sensors Actuators, B Chem., vol. 246, pp. 854–863, 2017.
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  • [18] M. D. Stanescu, S. Gavrilas, R. Ludwig, D. Haltrich, and V. I. Lozinsky, “Preparation of immobilized Trametes pubescens laccase on a cryogel-type polymeric carrier and application of the biocatalyst to apple juice phenolic compounds oxidation,” Eur. Food Res. Technol., vol. 234, no. 4, pp. 655–662, 2012.
  • [19] M. Çadırcı, K. Şarkaya, and A. Allı, “Dielectric properties of CdSe quantum dots-loaded cryogel for potential future electronic applications,” Mater. Sci. Semicond. Process., vol. 119, p. 105269, 2020.
  • [20] T. Shimizu, M. Masuda, and H. Minamikawa, “Supramolecular nanotube architectures based on amphiphilic molecules,” Chemical Reviews, vol. 105, no. 4. American Chemical Society , pp. 1401–1443, 2005.
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  • [25] X. R. Zhou, R. Ge, and S. Z. Luo, “Self-assembly of pH and calcium dual-responsive peptide amphiphilic hydrogel,” J. Pept. Sci., vol. 19, no. 12, pp. 737–744, 2013.
  • [26] W. Ha, J. Yu, X. Y. Song, J. Chen, and Y. P. Shi, “Tunable temperature-responsive supramolecular hydrogels formed by prodrugs as a codelivery system,” ACS Appl. Mater. Interfaces, vol. 6, no. 13, pp. 10623–10630, 2014.
  • [27] M. H. Hsiao, M.Larsson, A. Larsson, H. Evenbratt, Y. Y. Chen, Y. Y. Chen, and D. M. Liu, “Design and characterization of a novel amphiphilic chitosan nanocapsule based thermo-gelling biogel with sustained in vivo release of the hydrophilic anti-epilepsy drug ethosuximide,” J. Control. Release, vol. 161, no. 3, pp. 942–948, 2012.
  • [28] W. C. Huang, S. Y. Chen, and D. M. Liu, “An amphiphilic silicone-modified polysaccharide molecular hybrid with in situ forming of hierarchical superporous architecture upon swelling,” Soft Matter, vol. 8, no. 42, pp. 10868–10876, 2012.
  • [29] S. Song, L. Feng, A. Song, and J. Hao, “Room-temperature super hydrogel as dye adsorption agent,” J. Phys. Chem. B, vol. 116, no. 42, pp. 12850–12856, 2012.
  • [30] S. Das, P. Pandey, S. Mohanty, and S. K. Nayak, “Insight on Castor Oil Based Polyurethane and Nanocomposites: Recent Trends and Development,” Polymer - Plastics Technology and Engineering, vol. 56, no. 14. Taylor and Francis Inc., pp. 1556–1585, Sep. 22, 2017. [31] P. Anastas and N. Eghbali, “Green Chemistry: Principles and Practice,” Chem. Soc. Rev., vol. 39, no. 1, pp. 301–312, 2010.
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  • [34] R. L. Shogren, Z. Petrovic, Z. Liu, and S. Z. Erhan, “Biodegradation behavior of some vegetable oil-based polymers,” J. Polym. Environ., vol. 12, no. 3, pp. 173–178, 2004.
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  • [36] P. S. Sathiskumar and G. Madras, “Synthesis, characterization, degradation of biodegradable castor oil based polyesters,” Polym. Degrad. Stab., vol. 96, no. 9, pp. 1695–1704, 2011.
  • [37] S. Miao, P. Wang, Z. Su, and S. Zhang, “Vegetable-oil-based polymers as future polymeric biomaterials,” Acta Biomaterialia, vol. 10, no. 4. Elsevier BV, pp. 1692–1704, Apr. 01, 2014.
  • [38] G. Acik, M. Kamaci, C. Altinkok, H. R. F. Karabulut, and M. A. Tasdelen, “Synthesis and properties of soybean oil-based biodegradable polyurethane films,” Prog. Org. Coatings, vol. 123, pp. 261–266, 2018.
  • [39] B. Das, U. Konwar, M. Mandal, and N. Karak, “Sunflower oil based biodegradable hyperbranched polyurethane as a thin film material,” Ind. Crops Prod., vol. 44, pp. 396–404, 2013.
  • [40] B. Çakmakli, B. Hazer, T. Erdoğan, and A. G. Mutlu, “DNA adsorption and dynamic mechanical analysis of polymeric oil/oil acid copolymers,” J. Polym. Res., vol. 20, no. 3, pp. 1–11, 2013.
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There are 52 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Cansu Meltem Gürel This is me 0000-0003-3486-2074

Koray Şarkaya 0000-0003-0177-5134

Abdulkadir Allı 0000-0002-7164-5629

Project Number 2019.05.03.1024
Publication Date January 31, 2022
Published in Issue Year 2022 Volume: 10 Issue: 1

Cite

APA Gürel, C. M., Şarkaya, K., & Allı, A. (2022). Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, 10(1), 154-169. https://doi.org/10.29130/dubited.970641
AMA Gürel CM, Şarkaya K, Allı A. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. January 2022;10(1):154-169. doi:10.29130/dubited.970641
Chicago Gürel, Cansu Meltem, Koray Şarkaya, and Abdulkadir Allı. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi 10, no. 1 (January 2022): 154-69. https://doi.org/10.29130/dubited.970641.
EndNote Gürel CM, Şarkaya K, Allı A (January 1, 2022) Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 10 1 154–169.
IEEE C. M. Gürel, K. Şarkaya, and A. Allı, “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”, DUBİTED, vol. 10, no. 1, pp. 154–169, 2022, doi: 10.29130/dubited.970641.
ISNAD Gürel, Cansu Meltem et al. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Düzce Üniversitesi Bilim ve Teknoloji Dergisi 10/1 (January 2022), 154-169. https://doi.org/10.29130/dubited.970641.
JAMA Gürel CM, Şarkaya K, Allı A. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. 2022;10:154–169.
MLA Gürel, Cansu Meltem et al. “Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid”. Düzce Üniversitesi Bilim Ve Teknoloji Dergisi, vol. 10, no. 1, 2022, pp. 154-69, doi:10.29130/dubited.970641.
Vancouver Gürel CM, Şarkaya K, Allı A. Preparation, Characterization and İnvestigation of Swelling Behavior of HEMA-Based Amphiphilic Semi-IPN Cryogels Containing Polymeric Linoleic Acid. DUBİTED. 2022;10(1):154-69.